Hydrated Sulfate Clusters SO42–(H2O)n (n = 1–40): Charge Distribution Through Solvation Shells and Stabilization
نویسندگان
چکیده
منابع مشابه
Hydrated Lime Stabilization of Sulfate-bearing Soils in Texas
15. Supplementary Notes Research performed in cooperation with the Texas Department of Transportation and the Federal Highway Administration. Project Title: Develop Guidelines and Procedures for Stabilization of Sulfate Soils 16. Abstract Sulfate-bearing subgrade soils treated with calcium-based stabilizers often experience heaving problems (three-dimensional swell) due to chemical reactions w...
متن کاملElectron solvation in water clusters following charge transfer from iodide.
The dynamics following charge transfer to solvent from iodide to a water cluster are studied using time-resolved photoelectron imaging of I-(H2O)n and I-(D2O)n clusters with n< or =28. The results show spontaneous conversion, on a time scale of approximately 1 ps, from water cluster anions with surface-bound electrons to structures in which the excess electron is more strongly bound and possibl...
متن کاملThe Effect of Solvation on Electron Attachment to Pure and Hydrated Pyrimidine Clusters†
The interaction of low-energy electrons with biomolecules plays an important role in the radiation-induced alteration of biological tissue at the molecular level. At electron energies below 15 eV, dissociative electron attachment is one of the most important processes in terms of the chemical transformation of molecules. So far, a common approach to study processes at the molecular level has be...
متن کاملEffects of solvation shells and cluster size on the reaction of aluminum clusters with water
Related Articles Extended hydrodynamic approach to quantum-classical nonequilibrium evolution. II. Application to nonpolar solvation J. Chem. Phys. 136, 014102 (2012) Kinetics of azobenzene nitrene oxidation by molecular oxygen in glassy propylene carbonate J. Chem. Phys. 135, 244504 (2011) HNO3NHx, H2SO4NHx, CH(O)OHNHx, and CH3C(O)OHNHx complexes and their role in the formation of condensation...
متن کامل2À and its solvation stabilization
Despite its ubiquity in nature, SO4 22 as an isolated dianion has never been detected because of its electronic instability as a result of the two negative charges. This study shows how the first few waters solvate and stabilize an isolated SO4 , molecule-by-molecule, using photodetachment spectroscopy and theoretical calculations. We find that the minimum number of water required to stabilize ...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: The Journal of Physical Chemistry B
سال: 2019
ISSN: 1520-6106,1520-5207
DOI: 10.1021/acs.jpcb.9b01744